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Extension of pilot tests of cyanide elimination by ozone from blast furnace gas washing water through

Ismael Matino, Valentina Colla, Teresa A. Branca

《化学科学与工程前沿（英文）》 2018年第12卷第4期页码 718-730 doi: 10.1007/s11705-018-1771-2

摘要：

For improving wastewater quality, one of the dare of steelworks is reducing cyanide in wastewater of gas washing treatment of blast furnaces. Costs of existing treatments, stringent environmental regulations and changeable composition of water from gas treatment, have led to study how available treatments can be modified and to examine new ones. Ozonation is one of cyanide treatments, tested within a European project. A process model was set up with Aspen Plus^®, to assess operating conditions and wastewater distinctive characteristics and to demonstrate treatment robustness. Process was modeled by theoretical reactors, taking into account all more affecting reactions. A genetic algorithm was exploited to find kinetic parameters of these reactions. After validation, the model was used to analyse scenarios, by considering also real contexts. Pilot tests were extended, process knowledge was enhanced and suggestions were obtained. To promote cyanide removal with ozone, temperature and pH values were 30°C and 10, respectively. With an ozone (mg/h)/water (L/h) ratio of 100 mg/L, batch mode ensure reaching cyanide regulation limit (0.2 mg/L) after maximum 4.5 h, if initial amount was less than 20 mg/L. Higher removal was obtained than in continuous mode due to constraints related to this last run. Higher wastewater contamination needed further time and more ozone.

关键词： blast furnace cyanide removal gas washing water modeling and simulation ozonation

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高炉炼铁过程数据驱动软测量技术研究综述 Review Article

罗月阳1,张新民1,Manabu Kano2,邓龙3,杨春节1,宋执环1

《信息与电子工程前沿（英文）》 2023年第24卷第3期页码 327-354 doi: 10.1631/FITEE.2200366

摘要：在高能耗、高污染、极为复杂的冶炼过程中，高炉是极为重要的反应器。软测量技术是在线实时预测反映高炉能耗和运行稳定性质量指标的关键技术，在节能减排、提高产品质量和带来经济效益方面发挥着重要作用。随着物联网、大数据和人工智能的发展，高炉炼铁过程中的数据驱动软测量技术受到越来越多关注，但目前尚无关于高炉炼铁过程数据驱动软测量技术的系统性总结与评价。本文详细总结了高炉炼铁过程数据驱动软测量技术的最新研究成果与发展现状。具体而言，首先对高炉炼铁中使用的各种数据驱动软测量建模方法（如多尺度方法、自适应方法、深度学习等）进行了全面分类总结与分析。其次，对高炉炼铁中数据驱动软测量技术的应用现状（如硅含量、熔铁温度、气体利用率等）作对比分析。最后，展望了数据驱动软测量技术在高炉数字孪生、多源信息融合、碳达峰与碳中和等方面的潜在挑战和未来发展趋势。

关键词：软测量；数据驱动建模；机器学习；深度学习；高炉；炼铁过程

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Compressive strength and stability of sustainable self-consolidating concrete containing fly ash, silica fume, and GGBS

Osama Ahmed MOHAMED, Omar Fawwaz NAJM

《结构与土木工程前沿（英文）》 2017年第11卷第4期页码 406-411 doi: 10.1007/s11709-016-0350-1

摘要： This paper presents the findings of an experimental program seeking to understand the effect of mineral admixtures on fresh and hardened properties of sustainable self-consolidating concrete (SCC) mixes where up to 80% of Portland cement was replaced with fly ash, silica fume, or ground granulated blast furnace slag. Compressive strength of SCC mixes was measured after 3, 7, and 28 days of moist curing. It was concluded in this study that increasing the dosage of fly ash increases concrete flow but also decreases segregation resistance. In addition, for the water-to-cement ratio of 0.36 used in this study, it was observed that the compressive strength decreases compared to control mix after 28 days of curing when cement was partially replaced by 10%, 30%, and 40% of fly ash. However, a fly ash replacement ratio of 20% increased the compressive strength by a small margin compared to the control mix. Replacing cement with silica fume at 5%, 10%, 15%, and 20% was found to increase compressive strength of SCC mixes compared to the control mix. However, the highest 28 day compressive strength of 95.3 MPa occurred with SCC mixes in which 15% of the cement was replaced with silica fume.

关键词： fly ash silica fume ground granulated blast-furnace slag self-consolidating concrete and sustainable concrete

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Characteristics of the stabilized/solidified municipal solid wastes incineration fly ash and the leaching behavior of Cr and Pb

Yan SHAO,Haobo HOU,Guangxing WANG,Sha WAN,Min ZHOU

《环境科学与工程前沿（英文）》 2016年第10卷第1期页码 192-200 doi: 10.1007/s11783-014-0719-0

摘要： Fly ash is a hazardous byproduct of municipal solid wastes incineration (MSWI). An alkali activated blast furnace slag-based cementitious material was used to stabilize/solidify the fly ash at experimental level. The characteristics of the stabilized/solidified fly ash, including metal leachability, mineralogical characteristics and the distributions of metals in matrices, were tested by toxic characteristic leaching procedure (TCLP), X-ray diffraction (XRD) and scanning electron microscopy-energy dispersive spectrometer (SEM-EDS) respectively. Continuous acid extraction was utilized to extract metal ions and characterize their leaching behavior. The stabilization/solidification procedure for MSWI fly ash demonstrates a strong fixing capacity for the metals by the formation of C-S-H phase, hydrated calcium aluminosilicate and ettringite. The stabilized/solidified fly ash shows a dense and homogeneous microstructure. Cr is mainly solidified in hydrated calcium aluminosilicate, C-S-H and ettringite phase through physical encapsulation, precipitation, adsorption or substitution mechanisms, and Pb is mainly solidified in C-S-H phase and absorbed in the Si-O structure.

关键词： municipal solid waste incineration (MSWI) fly ash blast furnace slag leaching behavior Cr Pb

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一种基于数字孪生云平台的炼铁过程智能优化服务 Article

周恒, 杨春节, 孙优贤

《工程（英文）》 2021年第7卷第9期页码 1274-1281 doi: 10.1016/j.eng.2021.04.022

摘要：

工业过程多目标优化研究因算法和设备的不完善，已经大幅限制了工业过程的智能化发展。为了提升流程工业过程的操作水平，本文提出了一种基于云服务平台和分布式系统的混合智能优化框架。在这个智能优化系统中，工业实时数据首先暂存于本地服务器，经过清洗整理后上传至云数据库中；然后在可拓展的云平台上部署分布式系统用于运行智能优化算法；最后将基于深度学习和进化算法的多目标混合优化算法打包上传至云计算平台。通过将多目标优化服务运行于数字孪生云上工厂，钢铁厂高炉铁水产量增加了83.91 t·d^﹣1，焦炭比降低了13.50 kg·t^﹣1，硅含量平均降低了0.047%。

关键词：云上工厂高炉炼铁多目标优化分布式系统

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Simplified theoretical analysis and numerical study on the dynamic behavior of FCP under blast loads

Chunfeng ZHAO, Xin YE, Avinash GAUTAM, Xin LU, Y. L. MO

《结构与土木工程前沿（英文）》 2020年第14卷第4期页码 983-997 doi: 10.1007/s11709-020-0633-4

摘要： Precast concrete structures have developed rapidly in the last decades due to the advantages of better quality, non-pollution and fast construction with respect to conventional cast-in-place structures. In the present study, a theoretical model and nonlinear 3D model are developed and established to assess the dynamic behavior of precast concrete slabs under blast load. At first, the 3D model is validated by an experiment performed by other researchers. The verified model is adopted to investigate the blast performance of fabricated concrete panels (FCPs) in terms of parameters of the explosive charge, panel thickness, and reinforcement ratio. Finally, a simplified theoretical model of the FCP under blast load is developed to predict the maximum deflection. It is indicated that the theoretical model can precisely predict the maximum displacement of FCP under blast loads. The results show that the failure modes of the panels varied from bending failure to shear failure with the mass of TNT increasing. The thickness of the panel, reinforcement ratio, and explosive charges have significant effects on the anti-blast capacity of the FCPs.

关键词： precast structure fabricated concrete panel blast resistance theory model empirical equation

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Performance of soft-hard-soft (SHS) cement based composite subjected to blast loading with consideration

Jun WU,Xuemei LIU

《结构与土木工程前沿（英文）》 2015年第9卷第3期页码 323-340 doi: 10.1007/s11709-015-0301-2

摘要： This paper presents a combined experimental and numerical study on the damage and performance of a soft-hard-soft (SHS) multi-layer cement based composite subjected to blast loading which can be used for protective structures and infrastructures to resist extreme loadings, and the composite consists of three layers of construction materials including asphalt concrete (AC) on the top, high strength concrete (HSC) in the middle, and engineered cementitious composites (ECC) at the bottom. To better characterize the material properties under dynamic loading, interface properties of the composite were investigated through direct shear test and also used to validate the interface model. Strain rate effects of the asphalt concrete were also studied and both compressive and tensile dynamic increase factor (DIF) curves were improved based on split Hopkinson pressure bar (SHPB) test. A full-scale field blast test investigated the blast behavior of the composite materials. The numerical model was established by taking into account the strain rate effect of all concrete materials. Furthermore, the interface properties were also considered into the model. The numerical simulation using nonlinear finite element software LS-DYNA agrees closely with the experimental data. Both the numerical and field blast test indicated that the SHS composite exhibited high resistance against blast loading.

关键词： high strength concrete (SHS) engineered cementitious composite interface blast test strain rate effect

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Development of dimensionless P-I diagram for curved SCS sandwich shell subjected to uniformly distributed blast

Yonghui WANG, Ximei ZHAI

《结构与土木工程前沿（英文）》 2019年第13卷第6期页码 1432-1445 doi: 10.1007/s11709-019-0566-y

摘要： The curved steel-concrete-steel (SCS) sandwich shell was recently proposed to resist blast loading and it showed better blast resistant performance as compared to flat SCS sandwich shell via developing compressive force along the shell. In this paper, a dimensionless Pressure-Impulse (P-I) diagram was constructed as a convenient tool to predict the damage level of curved SCS sandwich shell subjected to uniformly distributed blast loading. The curved SCS sandwich shell was equivalent to a single-degree-of-freedom (SDOF) system and the equation of motion was established by employing the Lagrange’s equation. To construct the dimensionless P-I diagram, the energy balance method was utilized to yield the pressure and impulse asymptotes and the responses in the dynamic response regime were obtained via employing the SDOF method. Then, the finite element method was employed to validate the developed dimensionless P-I diagram. Finally, the procedures of using the constructed dimensionless P-I diagram to quickly conduct the blast resistant design of curved SCS sandwich shell were presented.

关键词： blast loading curved steel-concrete-steel sandwich shell Pressure-Impulse diagram single-degree-of-freedom method finite element analysis

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Simulation of blast induced crater in jointed rock mass by discontinuous deformation analysis method

Youjun NING, Xinmei AN, Jun YANG, Guowei MA,

《结构与土木工程前沿（英文）》 2010年第4卷第2期页码 223-232 doi: 10.1007/s11709-010-0022-5

摘要： Rock blasting is a dynamic process accompanied with the propagations of shock waves and the dispersion of the explosion gas. This paper adopts the discontinuous deformation analysis (DDA) method to simulate the rock blasting process. A dynamic parameter adjustment and the non-reflecting boundary condition are implemented in the DDA method. The sub-block DDA method to simulate fracture problems is used. The blasting process in jointed rock mass is simulated by application of the explosion gas pressure on the expanding borehole walls and induced connected fracture surfaces around the boreholes. The blast craters with different overburdens are derived. The whole process including the explosion gas dispersion, borehole expansion, rock mass failure and cast, and the formation of the final blasting piles in rock blasting are well reproduced numerically. Parametric study for different overburdens is carried out, and the results are analyzed and discussed.

关键词： blast crater jointed rock mass explosion gas pressure discontinuous deformation analysis (DDA) method

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Prediction of characteristic blast-induced vibration frequency during underground excavation by using

Tae Un PAK; Guk Rae JO; Un Chol HAN

《结构与土木工程前沿（英文）》 2022年第16卷第8期页码 1029-1039 doi: 10.1007/s11709-022-0861-x

摘要： Blast-induced vibration produces a very complex signal, and it is very important to work out environmental problems induced by blasting. In this study, blasting vibration signals were measured during underground excavation in carbonaceous shale by using vibration pickup CB-30 and FFT analyzer AD-3523. Then, wavelet analysis on the measured results was carried out to identify frequency bands reflecting changes of blasting vibration parameters such as vibration velocity and energy in different frequency bands. Frequency characteristics are then discussed in view of blast source distance and charge weight per delay. From analysis of results, it can be found that peak velocity and energy of blasting vibration in frequency band of 62.5–125 Hz were larger than ones in other bands, indicating the similarity to characteristics in the distribution band (31–130 Hz) of main vibration frequency. Most frequency bands were affected by blasting source distance, and the frequency band of 0–62.5 Hz reflected the change of charge weight per delay. By presenting a simplified method to predict main vibration frequency, this research may provide significant reference for future blasting engineering.

关键词： wavelet analysis blast-induced vibration frequency characteristics underground excavation

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Dynamic failure analysis of concrete dams under air blast using coupled Euler-Lagrange finite element

Farhoud KALATEH

《结构与土木工程前沿（英文）》 2019年第13卷第1期页码 15-37 doi: 10.1007/s11709-018-0465-7

摘要： In this study, the air blast response of the concrete dams including dam-reservoir interaction and acoustic cavitation in the reservoir is investigated. The finite element (FE) developed code are used to build three-dimensional (3D) finite element models of concrete dams. A fully coupled Euler-Lagrange formulation has been adopted herein. A previous developed model including the strain rate effects is employed to model the concrete material behavior subjected to blast loading. In addition, a one-fluid cavitating model is employed for the simulation of acoustic cavitation in the fluid domain. A parametric study is conducted to evaluate the effects of the air blast loading on the response of concrete dam systems. Hence, the analyses are performed for different heights of dam and different values of the charge distance from the charge center. Numerical results revealed that 1) concrete arch dams are more vulnerable to air blast loading than concrete gravity dams; 2) reservoir has mitigation effect on the response of concrete dams; 3) acoustic cavitation intensify crest displacement of concrete dams.

关键词： air blast loading concrete dams finite element dam-reservoir interaction cavitation concrete damage model

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炉内废气循环气体浓度新模型检测方法研究

沈远胜,刘永杰,王德永,李本文

《中国工程科学》 2005年第7卷第5期页码 70-72

摘要：

通过分析炉内废气循环过程的特点，在一定废气循环量的条件下，建立了炉内废气容积流量与废气循环次数的定量数学关系，建立了废气中氧气浓度与循环次数的定量数学关系。运用数学极限定律，得出氧的极限浓度定量数学公式，以此为基础，建立了助燃剂中氧气的浓度以及可燃混合物中氧气的浓度定量数学关系式。并以此推导出其他成分浓度的计算数学模型，为实际生产过程中不同环节的气体成分检测、分析建立了基础。

关键词：检测模型燃烧物燃烧比循环炉

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An investigation of reaction furnace temperatures and sulfur recovery

S. ASADI, M. PAKIZEH, M. POURAFSHARI CHENAR

《化学科学与工程前沿（英文）》 2011年第5卷第3期页码 362-371 doi: 10.1007/s11705-011-1106-z

摘要： In a modern day sulfur recovery unit (SRU), hydrogen sulfide (H S) is converted to elemental sulfur using a modified Claus unit. A process simulator called TSWEET has been used to consider the Claus process. The effect of the H S concentration, the H S/CO ratio, the input air flow rate, the acid gas flow of the acid gas (AG) splitter and the temperature of the acid gas feed at three different oxygen concentrations (in the air input) on the main burner temperature have been studied. Also the effects of the tail gas ratio and the catalytic bed type on the sulfur recovery were studied. The bed temperatures were optimized in order to enhance the sulfur recovery for a given acid gas feed and air input. Initially when the fraction of AG splitter flow to the main burner was increased, the temperature of the main burner increased to a maximum but then decreased sharply when the flow fraction was further increased; this was true for all three concentrations of oxygen. However, if three other parameters (the concentration of H S, the ratio H S/CO and the flow rate of air) were increased, the temperature of the main burner increased monotonically. This increase had different slopes depending on the oxygen concentration in the input air. But, by increasing the temperature of the acid gas feed, the temperature of the main burner decreased. In general, the concentration of oxygen in the input air into the Claus unit had little effect on the temperature of the main burner (This is true for all parameters). The optimal catalytic bed temperature, tail gas ratio and type of catalytic bed were also determined and these conditions are a minimum temperature of 300°C, a ratio of 2.0 and a hydrolysing Claus bed.

关键词： Claus unit concentration of H₂S tail gas ratio sulfur recovery catalytic bed

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高品质铝合金汽车板预处理气垫炉技术

李勇,王昭东,马鸣图,王国栋,付天亮,李家栋

《中国工程科学》 2014年第16卷第1期页码 14-22

摘要：

首先介绍了铝带预处理的原理、工艺特点及气垫炉的工作原理，研究了汽车板生产工艺流程中的难点和重点，指出了气垫炉的工艺位置和不可替代的重要作用；回顾了铝带气垫炉生产线的发展过程，并对其进行了阶段划分和总结；分析了铝带气垫炉的研究现状，对其关键技术进行了深入分析，提出了铝合金汽车板气垫炉技术今后在工艺、设备及控制模型方面的研究重点。随着汽车行业轻量化的快速发展，汽车用铝带气垫炉装备、生产工艺技术的研究与开发必将迎来一个新的发展阶段。

关键词：铝合金汽车板沙特板气垫炉预处理工艺